Angelina of course looked immaculate in an asymmetric floor-sweeping Saint Laurent gown complete with simple black heels and minimal jewellery. The actress also kept her long hair swept back off her face and let her tresses loose.
The Salt starlet also opted for smokey eye make-up and nude glossy lips while husband Brad Pitt looked super-smart in a black tailored ensemble showing off his goatee beard and new blonde locks.
The couple, who have six children together, also spent time laughing and joking before entering after Angelina had also spent time promoting her latest movie, In The Land of Blood and Honey earlier that day.
Watch: Angelina Jolie on the red carpet...